Here is a quick and dirty way of finding out the binding order of your multi-homed server (meaning a server with multiple NICs or multiple network ports). On a command prompt run ipconfig. All active connections will be shown in the current binding order. The first entry is the one in the top of the binding order and so and so forth. The ports which are not connected are not shown here. This is especially useful if you are running server core (without GUI) and quickly want to find out this info.